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On-demand monocationic Ir(III) octahedron builder

Combine any κ²-N,N / κ²-C,N / κ²-C,C bidentate chelates from the ligand library or enter your own ligand SMILES into an octahedral Ir(III) complex. The server assembles the octahedral template on request (deterministic, no xtb) and returns a real bond-block structure.
Monocationic rule. Ir(III) is +3. A monocationic (+1) octahedron needs the three chelate charges to sum to −2 → pick two anionic (−1) chelates + one neutral (0) chelate. All distinct diastereomers are enumerated (T-REX); each chiral one is built as one enantiomer with the mirror available on request.

Anionic chelate #1 (−1)

none selected
Charge must be encoded in SMILES; donor atoms are resolved automatically.

Anionic chelate #2 (−1)

none selected
Charge must be encoded in SMILES; donor atoms are resolved automatically.

Neutral chelate (0)

none selected
Charge must be encoded in SMILES; donor atoms are resolved automatically.
charge = +3 + (−?) + (−?) + (?)
presets: